I'm pretty sure that it's your transmission fluid mixing with your coolant, and coolant also going into your auto transmission which will end up stuffing it. This is common with crappy alloy radiators with crappy built in alloy transmission oil coolers which stuff up through corrosion and begin mixing auto trans fluid with the coolant and vice versa.
This problem you have will only get worse as time goes by because the leaking gets bigger and bigger, and you'll have more and more gunk, and you'll lose more and more water till your trans stops working one day, amongst other things!
This is usually always the case when it isn't your head gasket causing the gunk. and if you have a nice clean oil filler cap, your head gasket is not causing the gunk on your rad cap. It's trans fluid.
Best fix is to throw away your alloy radiator and install a brand new copper core radiator made for manual trans which has no connections for trans cooling lines (you wont be needing them). Then install an external auto trans oil cooler in front of the air con condenser which of course will totally bypass the radiator so you can never have this problem again, plus you'l
This works perfectly well in winter and summer, as transmissions love to be cool not hot.
I did this myself about 4 years ago and it's one of the best things I've ever done to our car.
Some cars come out standard with this setup. Every auto transmission should come factory liker this in my opinion.
You will still get that gunk on your rad cap for a long time as it has trans fluid right throughout your motor. just keep cleaning your cap every couple of weeks till there is no more gunk. it will take a long time to get totally rid of it!
Don't forget to flush your motor really well before installing your new radiator, and use 5 litres of good quality long life concentrate coolant in your system. I chose the green coloured Nulon concentrate coolant which lasts 4 years or 100,000 Klms I think?? Thats just running off memory but it's something like that. In my opinion and many other people I know including good mechanics, it's top notch coolant! Don't buy cheap crap just to save a few bucks!
Anyway, good luck people, and I hope that my experience will help many of you!!!!!!!