Caster is a greater value on the left, to counter the camber of the road....Roads are sloped to the left, to allow water to run off easier..(in theory anyways, but not always in practice), so the front left is further forward to counteract this slope (camber)....
Washer placement....With aftermarket kits, they have 3 different thickness washers...Generally on the left,, you put the thinner washer lower control arm side of the radius rod behind the large factory style washer, to help them drive straight.
With factory washers....There are only 2 large ones so difficult to mix them up...Just make sure, the left and right are done seperately, so not to mix them up.....However over the years, I have found that the radius rod (or Z bar as it is also called) straightens out, so the caster on the left is equal or less than the right, so the car tends to drift left....So a quick fix is, put another 1 or 2 factory style washer/s lower control side of the K-frame. This applies with all Commodores, from VB through to VF and is perfectly safe....
As for the issue of not centring....I'd be looking at the top strut mounts being the cause first......Make sure they are moving freely....Then move to the control arm making sure it is greased up, at the K-frame mounting point....If they're all good, unfortunately it'd be the rack....Honestly I seriously doubt it'd be an alignment issue in anyway, but it is a remote possibility