Pollushon, your point is understood but as straight glycol has no water in it, does altitude really affect it? Even if there was water in it, those and todays engines run a pressurized system to raise the boiling point to well over sea level air pressure (boiling point, 212F 100C).
Hang on, you asked why pressurised liquid cooled piston powered aircraft use straight glycol without water and I answered it. Pressurised liquid cooled aircraft run much lower pressure cooling systems to cars because of the strains it undergoes with altitude (therefore air pressure) changes, which as it climbs increases pressurisation on the system, while outside pressure and temperature decreases.
Some of these craft have a service ceiling of 20k + ft. At 20k ft, water boils at around 70c. Glycol doesn't. So you run a low pressure 100% glycol cooling system and there's far less chance of falling out of the sky. You'd need serious PSI to raise the boiling point of water at that altitude which then cops a shitload of stress when you descend and especially climb, then repeat the process again. You could pop it like a balloon.
That said many, many aircraft run air cooling over liquid because it's not hard to air cool an engine with an IAS of 200kn + running over it. The compromise is HP.
Going back in history a bit but the Spitfires and Lancaster bombers of WW2 both used the Rolls Royce V12 engine with straight glycol coolant and were the most reliable engines of the time.
As did the Hurricane, P38, Mosquito, Typhoon/Tempest, Yak, IL2 and most combat craft of WWII. The Griffon engine reliability had very little if nothing to do with the cooling solution, they were just simplistic, robust and very powerful. That said, a throttle happy pilot could blow one to smithereens if he didn't watch his RPM, torque and mix ratio. They'd also overheat if left idling on the ground for more than 5 minutes. The low pressure liquid cooling was the absolute best solution for such aircraft though, they'd be under full power (or more), zipping, spinning, dropping and climbing constantly.
Short answer, Glycol provides less efficient cooling than water but it's more stable and reliable. Comparing aircraft to cars is beyond chalk and cheese.