The best check for a functioning cat is a temperature test. Take the car to an exhaust shop and ask for a cat test. They should drive it around the block to get the cats hot, then take a temperature reading at the front of each cat and directly behind them. The temp at the rear should be at least 10% hotter than the front, if it's about the same or colder then the cats are not working. Just because the sensors say the cats aren't working doesn't mean they aren't sensors only read what they can read. They are a good guide but diagnosis or replacing parts should not be 100% reliant on what a sensor or a code tells you. It just tells you where to look.
Oh, and cats can't "blow", they either wear out or melt and block up. An OEM cat, by law, only has to last 80,000km, aftermarket 40,000km. 191,000km is good, but having said that, a well maintained car will see cats last almost indefinitely, there are always outside factors that cause cats to fail.