^^^ sort off.
The double row timing chain kits do come with timing marks.
Double row chain is recommended with the #105lbs springs (stage 2 comp cams recommended) and a must with the #130lbs springs.
You will need to remove the 4 large bolts for the water pump, however you don't need to remove the actual water pump from the timing case which is held in place by another 5 smaller bolts. On the other hand, if the water pump is getting old then replacing it at the same time won't hurt, fit a new thermostat at the same time.
If you remove the intake manifold carefully you can minimise any coolant getting into the oil, I would however recommend changing the oil fairly soon after doing a cam change if your not certain about the quantity of coolant getting into the oil. A small amount of coolant will get burnt off fairly quickly.
If you turn the engine over and line up the timing marks on the original timing chain gears you will ensure the engine is at TDC which will make fitting a new cam fairly easy.
Yes, a doubling up the gasket is generally enough to ensure clearance for the timing chain, the other option is to buy the oil pump cover from MACE that has been machined for extra clearance.