This is where it got confusing, but regardless, I have ultimately "fixed" this problem in a way that costs practically nothing..
The two brand new, identical Delco solenoid packs arrived and I replaced the assumed faulty unit with one of them.
The problem of switching vents that the Plasticine fixed returned immediately.
I figured I had been sent a faulty unit so I swapped in the other brand new Delco unit and same problem existed.
Both units bleed air from the vent at the rear of #3, 4 & 5 solenoids during different modes.
The fix..
A 3/4" length of electrical/pvc tape over the rear of the #4 solenoid. This prevents that solenoid leaking vacuum during "face mode".
Open up the black plastic case and put the tape over the port in the same way I Plasticined in the above pic.
Bear in mind that this is the solenoid pack of a WH.
On a VT or other model, open up the black case, remove the solenoid pack, reconnect the hoses and connector and start the car with the A/C on and in "face mode".
With your finger, find out which of the solenoids is leaking. Tape it, reinstall, and hopefully happy days.
As for the real fault/s? Maybe it's an actuator, or something else.
Anyway, I have decided that I don't care as the problem is fixed, and I am certainly not about to embark on the nightmarish job of pulling the dash apart and swapping about $250-300 bucks worth of parts that are probably not faulty either, only to learn that it's still something else.
Chances are your solenoid pack is fine.
Good luck.
IF buy chance your solenoid pack is actually faulty and you have a VN-VS, or a WH and need a new pack.
I bought 2 on Amazon landed for AU$150.
Yes they are the same with the new having a superseded part number.