Could well be a burnt valve. At those kms, the seats begin to round away and this gives poor sealing and heat transfer out of the body of the exhaust valve, into the cylinder head seat suffers due to the reduced seating area.
The valve then heats up, with poor cooling and sealing and you have a recipe for a burnt valve.
Best way to diagnose is to swap ignition leads on the affected cylinder. If no change, then its not the spark plug lead.
Next, remove the spark plug, still attached to the spark plug lead, hold it against the cylinder head to ground it, crank the engine and check for spark on that plug.
If it passes both those tests, I would strongly suspect a burnt valve. To test this, compression test all six cylinders and I bet you find very low compression on the suspect cylinder. That would likely indicate a burnt valve.
Source: Cylinder head machinist with my own machine shop. No longer in business, but have kept all my machinery and do small private machining jobs at times. I now work in an office.