Rhodopsin is the key to night vision -- it is the chemical that the rods use to absorb photons and perceive light. When a molecule of rhodopsin absorbs a photon, it splits into a retinal and an opsin molecule. These molecules later recombine naturally back into rhodopsin at a fixed rate, and recombinati#on is fairly slow.
So, when you expose your eyes to bright light, all of the rhodopsin breaks down into retinal and opsin. If you then turn out the lights and try to see in the dark, you can't. The cones need a lot of light, so they are useless, and there is no rhodopsin now so the rods are useless, too. Over the course of several minutes, however, the retinal and opsin recombine back into rhodopsin, and you can see again.
A fun fact: The retinal used in the eye is derived from vitamin A. If a person's diet is low in vitamin A, there is not enough retinal in the rods and therefore not enough rhodopsin. People who lack vitamin A often suffer from night blindness -- they cannot see in the dark.