It gets bloody cold here early in the morning where I live, its been minus 3 to minus 4 degrees C the last few mornings, and my windscreen on my VS is always iced up heaps on the outside, and fogged up heaps on the inside. I just throw some cold water on the outside and run the wipers to clear the ice, then I set the heater to hot with the A/C switched on, and the blower fan set on 2. This easily demists the inside of the car within a minute or two. I also run the rear defogger for 15 minutes or so to help de ice and demist the rear window. If you are already running the A/C with the heater on hot and its not demisting the glass, its probably worth getting the heater and A/C checked out.
The workshop manuals says that these A/C systems may need periodic regassing every couple of years or so to keep the A/C system working at its best. As mentioned above in another post, the A/C doesnt just cool air, it also removes the moisture from it, or "dries" it, which is why it demists the interior glass so well when its working correctly.