I shudder at E10, not good for an LS3, luckily my company fuel card let me use at least 91 unleaded and better. Like you, I do a fair bit of k's for work.
I have a VF2 Redline sedan and keep the same sort of data in my phone with the Fuelio app. I drive around Sydney, mixed city and highway.
Whats interesting is that I've recently discovered that I get better economy on the whole from my local BP with 98 ultimate. So I'll stay with BP for a couple tanks and then try a random Caltex again to see if theres a change.