I had a VP calais. The switch on the door only turns the alarm off. Not the immobiliser. If you don't have the the correct key fob, the car will not start. Hence why you are not getting spark.
If you do have the correct key fob and the doors unlock when you press the remote, then you can rule out security/bcm issues and start looking into electrical issues as everyone has suggested (coil, dizzy, ignition module, earths and then ecu as last resort). If all those things check out ok then one thing I would try, is running 12v directly to the coil and kick it over a couple times to see if it fires and check to see if it's getting spark by taking out one of the spark plugs and earthing it to the engine.